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C4 Alkenes. Several industrial processes have been developed for olefin production through catalytic dehydrogenation 138 ,166,167 of C4 alkenes. All four butenes are valuable industrial intermediates used mostly for octane enhancement. Isobutylene, the most important isomer, and its dimer are used to alkylate isobutane to produce polymer and alkylate gasoline (see Section 5.5.1). Other important utilizations include oxidation to manufacture maleic anhydride (see Section 9.5.4) and hydroformylation (see Section 7.1.3). The high demand for oxygenates, especially for MTBE, in new gasoline formulations called for a substantial increase in the capacity of isobutylene production in the early 1990s. As a result, new processes emerged to manufacture isobutylene through the dehydrogenation of isobutane. Four technologies employing noblemetal-based catalysts or chromia on alumina were developed. 164 The Oleflex processl60-162 applies platinum on basic alumina and operates at higher severity than the Pacol process from which it is derived. Modification of the original catalyst systems was required to decrease skeletal isomerization and coke formation. 161 Isobutylene is produced with a selectivity of 91-93%. The Phillips STAR dehydrogenation process l63 ,164 also employs a noble metal catalyst. Users of the FBD-4 (Snamprogetti) fluidized-bed process with a promoted chromium oxide catalyst 168 are located primarily in the former Soviet Union. The Catofin process I69- 171 is based on the Houdry Catadiene technology, which was developed in the 1940s to produce 1,3-butadiene from butane over a chromium oxide-alumina catalyst. Dehydrogenation of isobutane to isobutylene is carried out over chromia-alumina at 500-675 C in vacuo to achieve high conversion.

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In these expressions, max is the maximum local scan angle. Dividing by the total area 2 R2, we get the performance-to-cost index shown in Figure 3.13 as a solid line. The gradual reduction in performance from the 30 scan angle and onward is due to the cutoff of the lower part of the hemisphere (see Figure 3.4). One alternative is to extend the sphere downward to make the effective area constant with scan. However, this significantly increases the total area and, hence, the cost. The performance index (effective area/total area) reduces to 0.20 (the dashed line in Figure 3.13). 3.3.4 Cone A conical shape can be used for hemispherical coverage provided it is not too pointed or too blunt. Since we imposed a maximum element look angle of 60 , the total cone angle t [see Figure 3.14 (a)] must be in the interval from 60 to 120 . The total cone surface is Atot = R2 sin

Make/Release Clipping Mask. This button, which looks like an overlapping rectangle and circle, lets you create a clipping mask in the layer. The topmost object in the layer acts as the masking shape. The difference between using Make/Release Clipping Mask from the Layers panel rather than choosing Object Clipping Mask Make is that the objects won t be grouped when using the Layers panel.

You may find working with a drawing in Outline mode significantly faster than working with it in Preview mode. In more complex drawings, the difference between Outline mode and Preview mode is significant, especially if you re working on a very slow computer. This is even more noticeable when the artwork contains gradients, patterns, placed artwork, and blends. Outline mode is much closer to what the printer sees as paths. Paths define the edges of the objects with which you re working.

One last bit of code is necessary. To ensure that a value is within the acceptable range, a fourth Multiple-If clause is required for error-checking purposes. In this clause, if the selectCSS template parameter entered at design time is less than 1 or greater than 3, the default style sheet is applied:

Intermaterial area density ( )

3. If you have more than two radio buttons in your set, click the Add (+) button to add another item to the list and fill out the appropriate value, as explained in step 2. 4. Specify whether you want your radio buttons inserted on separate lines using the <br> tag, or automatically formatted in a table. 5. Finally, click OK.

As you work through the programs and hacks in this book, you may choose to either type in all the code manually or to use the source code files that accompany the book. All of the source code used in this book is available for download at the following site:

10-3.1.3 Effect of Fluid Particle Size. Several studies (Zolfagharian, 1990; Choudhury et al., 1995; Choudhury, 1997) indicate that the effect of particle diameter is not as simple as the Zwietering correlation suggests, particularly at solid loading less than about 5 wt%. The exponent reported by Zwietering appears to be an average value for dp between 0.20 and 1 mm. For particles greater than about 1 mm in diameter, Njs appears to be unaffected by the particle size. Choudhury reported this critical particle in terms of dp /D at a value of about 0.01. On the other hand, for particles smaller than 0.20 mm, the average value of the exponent was about 0.5. 10-3.1.4 Effect of Vessel and Impeller Geometry and Scale. The effects of the geometry of the impeller, vessel, and its internals are subsumed in the

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