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When two electrons have the same spin, the state is a triplet, designated T1 Y T2 Y F F F Y in order of increasing energy, or by a superscript in front of the state descriptor, for example, 3 nO p The spatial symmetry of the state is, in practice, determined by the cross product of the spatial symmetries of the SOMOs by the following rules: S S A S, A A A S, S A A A, A S A A The ``closed-shell'' states, like the ground state, are S with respect to every symmetry operation or transform as the totally symmetric irreducible representation of any point group The energies of the electronic states may be derived from simple Huckel consid erations (MO energy di erences) Triplet states are lower than the singlets with the same MO con guration.

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x(t) =

UKHO Tidal Predictions In many parts of the United Kingdom, the tidal curve is skewed, and along parts of England s south coast, the curve is far from smooth, especially due to the ow up and down the channel and the in uence of the Isle of Wight.

Uniform: Select this option to apply colors absolutely randomly within the specified range. Photoshop is no more likely to apply one color within the range than another, thus resulting in an even color distribution.

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The separation of 3 nO p and 1 nO p is relatively small, whereas the separation of 3 pp and 1 pp is large Singlet states may be reached directly from the ground state by photoexcitation at the appropriate frequency The electron rearrangement associated with the excitation process is very rapid (about 10 15 s), and the nuclei do not have time to move to their new equilibrium positions The dynamics of the excitation process and the fate of excited electronic states are discussed in 15 Rules for Correlation of Electronic States When the electronic states of both the reactants and products have been determined and characterized, a correlation diagram may be constructed by connecting the states according to the following rules: 1 As with orbital correlation diagrams, states are correlated from the lowest to the highest 2.

Definition 4.1 The M x N covariance matrix of the M x 1vector u and the N x 1 vector v is defined as (4.11) COV(U,v ) = E [ ( u- Eu)(v- Ev)*]

of explanation, the last two of Maxwell equations are rewritten as curl E(r,t) = -popr- w r , t) at curlH(r, t) =

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Reactant states will only correlate with product states of the same spatial symmetry and spin multiplicity 3 Correlation lines de ne potential energy ``surfaces'' Surfaces are allowed to cross (intersect) if the states involved are di erent in spatial symmetry or spin multiplicity but may not cross if both characteristics are the same 4 Inspection of the orbital make-up of reactant and product states may imply intended correlations which would lead to state crossings If the states involved may not cross by rule 3, an avoided crossing occurs The intention to cross is often depicted by dashed lines Example: Carbene Addition to an Olefin The MOs and electronic states of carbene have been discussed in 7 The orbital and state correlation diagrams for addition of :CH2 to ethylene is shown in Figure 149.

There is considerable ethnic variation in the relationship between adiposity and the sequelae of obesity, and these can confound the attribution of risk to measures such as BMI and waist circumference. Of particular note is the higher risk of type 2 diabetes in Asian and American

The drawback of the Fade command is that it s only available immediately after you apply a filter (or other applicable edit). If you so much as modify a selection outline after applying the filter, the Fade command dims, only to return when you apply the next filter. Therefore, you may find it more helpful to copy a selection to a separate layer (Ctrl+J) before applying a filter. This way, you can perform other operations, and even apply many filters in a row, before mixing the filtered image with the underlying original.

2 2 2 2 2

The Walsh bonding picture for the MOs of cyclopropane requires that the s and s MOs of the ethylene also be included in the diagram The s2 and s3 orbitals are degenerate but are shown separated for clarity The postulated least-motion pathway preserves a vertical plane of symmetry (as well as the other elements of the C2v point group), and the.

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